Acetal, or polyacetal, is a widely used material for anti-extrusion rings, bearings and structural components. It has better capability, lower water absorption and wider temperature capabilities than polyamide (Nylon).
Acetal is available with a wide range of fillers
Strength may be improved by many types of filler from glass to stainless steel
Lubrication may be improved by the addition of PTFE, MoS2, or carbon
The incorporation of fillers will have significant effects on the mechanical properties
This elastomer is a copolymer of tetrafluoroethylene (TFE) and propylene. The fluorine contributes to the good fluid resistance and temperature capability, but the ethylene base causes higher swell in hydrocarbon liquids than experienced with fluorocarbons.
Aflas™ is found in numerous applications in the oilfield industry
Aflas has poor low temperature performance and low resilience
Lighter aromatic hydrocarbon liquids (gasolines), solvents such as benzene, ethers and ketones, chlorinated solvents and hydrocarbons, refrigerants, kerosene
CARBOXYLATED NITRILE ( CBX , XNBR )
Trade names:
Temp. Range:
-20°C to + 135°C
-4°F to + 275°F
Description:
The addition of carboxylic acid groups to the NBR polymer backbone produces a polymer with increased strength, which provides a material with improved tensile and wear properties plus good abrasion resistance. The negative effects include reduction in compression set and water resistance, resilience and some low temperature properties.
Lower solvent swell
Excellent chemical resistance to petroleum oils and fluids
Commonly used in dynamic applications
Suitable with:
Aliphatic hydrocarbons (propane, butane, petroleum oil,mineral oils and grease, diesel fuels, fuel oils), LPG, water and glycol-based and (HFA, HFB and HFC) hydraulic fluids, vegetable oils
Not suitable with:
Aromatic hydrocarbons (benzene, high octane gasoline, etc.), chlorinated hydrocarbons, polar solvents, glycol-based brake fluids, ozone and weather aging, stong acids, hot water, ozone, water, atmospheric aging
CHLOROPRENE ( CR )
Trade names:
DuPont Performance Elastomers - Neoprene, Lanxess AG - Baypren®
Temp. Range:
-40°C to +121°C
-40°F to +250°F
Description:
Chloroprene (from DuPont™) was the first synthetic elastomer material developed commercially. It exhibits generally good ozone, aging and chemical resistance. It also has good mechanical properties which it retains reasonably over a wide temperature range.
It is commonly found as a seal material in compressed air systems and is one of the few elastomers with good resistance to R12
Today there are at least nine different manufacturers of polychloroprene
Suitable with:
Paraffinic mineral oils, silicone oils, water, refrigerants, ammonia, weather, ozone
Not suitable with:
Aromatic and chlorinated hydrocarbons, polar solvents, toluene
There are two different types of EP rubber: EPM and EPDM.
EPM - Copolymer of ethylene and propylene
EPDM - Terpolymers of ethylene, propylene and a diene
Ethylene propylene based materials are resistant to some fluids that cause problems with most other elastomers. The major limitation is the complete lack of resistance to hydrocarbon liquids. Therefore, they should be handled with some care in a work shop environment.
Useful when sealing phosphate-ester hydraulic fluids and glycol based brake fluids
The major limitation to performance in high temperature applications is the air aging resistance
EPM's are generally cured with organic peroxides
EPDM's are either cured with conventional sulfur cure systems or organic peroxides
Suitable with:
Water, steam, phosphate ester (HFD-R and Skydrol), silicone oil and grease, polar solvents, glycol-based brake fluids, some acids and alkalis, ozone, air ageing
Not suitable with:
Mineral oil products (oils, greases and fuels), air ageing and ozone at high temperatures
FLUOROCARBON ( ETP , TBR )
Trade names:
DuPont Performance Elastomers - Viton® Extreme™
Temp. Range:
-20°C to +204°C
-4°F to +400°F
Description:
Viton® Extreme™ is a fluorocarbon compound that exhibits significantly improved performance over regular Viton® Fluorocarbons are a high temperature oil resistant elastomer capable of providing a very wide chemical compatibility range. There are several different fluorocarbon compounds available. The basis of the different compounds is the incorporation of fluorine into the polymer chain. As you increase the fluorine concentration within the polymer, the greater the chemical resistance of the compound.
TBR - Totally Base Resistant compound that provides improved performance over other TFE/Propylene polymers
ETP - Provides the excellent thermal resistance of Viton along with significantly advanced chemical resistance
Suitable with:
Mineral oils and greases, HFD, silicone oils and greases, vegetable oil and grease, aliphatic and aromatic hydrocarbons, chlorinated hydrocarbons, gasoline, ozone, weather, ageing
Not suitable with:
Glycol-based brake fluids, steam and hot water above 100 ºC, Skydrol, polar solvents, ammonia, methanol, amines, alkalis, organic acids
FLUOROCARBON ( FKM )
Trade names:
DuPont Performance Elastomers - Viton® DuPont™
Temp. Range:
-26°C to +204°C (Low Temp. available to -40 ºC)
-15°F to +400°F (Low Temp. available to -40 ºF)
Description:
Fluorocarbons are a high temperature oil resistant elastomer capable of providing a very wide chemical compatibility range. There are several different fluorocarbon compounds available. The basis of the different compounds is the incorporation of fluorine into the polymer chain. As you increase the fluorine concentration within the polymer, the greater the chemical resistance of the compound. Fluorocarbons were originally developed as a dipolymer of hexafluoropropylene (HFP) and vinylidene fluoride (VDF). These comprise the Viton® A and GA polymers from DuPont Performance Elastomers.
Hi-Tech's main compound is A-401C from Dupont, it is 66% fluorinated and bisphenol cured. It has good hydrocarbon and compression set resistance
Terpolymers were developed by adding tetrafluoroethylene (TFE) to the HFP-VDF co-polymer which results in 68% fluorine content. These are the Viton® B grade. They provide improved fluid resistance but inferior compression set and low temperature performance
Viton® GF compounds are also available and contain approximately 69-70% fluorine
Viton® GLT provides the same excellent resistance to heat and fluids that is typical of the Viton® A grade but also exhibits significantly improved low temperature flexibility
Viton® GFLT is similiar to Viton® GLT but in addition provides improved chemical resistance
Generally an increase in fluorine content provides improved fluid resistance but has been associated with a reduction of the physical properties
Suitable with:
Mineral oils and greases, HFD, silicone oils and greases, vegetable oil and grease, aliphatic and aromatic hydrocarbons, chlorinated hydrocarbons, gasoline, ozone, weather, ageing
Not suitable with:
Glycol-based brake fluids, steam and hot water above 100 ºC, Skydrol, polar solvents, ammonia, methanol, amines, alkalis, organic acids
FLUOROSILICONE ( FVMQ , FMQ )
Trade names:
Dow Corning - Silastic® LS/FSR, GE Silicones - Silplus®
Temp. Range:
-56 ºC to +204 ºC
-69 ºF to +400 ºF
Description:
Fluorosilicone has fluorine added into the polymer chain in order to provide improved chemical resistance over silicone. Flurosilicone also has similiar mechanical properties to silicone.
Generally low tear strength, abrasion resistance and tensile strength
Generally not suited for dynamic applications
Suitable with:
Mineral oils and greases, silicone oils, synthetic lubricants, ATF, brake fluids, water, alcohol
Highly saturated nitrile (also known as hydrogenated nitrile) is the result of the nitirile polymer being subjected to the hydrogenation process which has the effect of improving the resistance of the polymer chain to chemical attack. HNBR has a wider temperature range than standard nitrile and good mechanical properties. However, it will cost more than standard nitrile.
High strength material that resists extrusion, abrasion and wear
Popular for seal applications in the oil and gas industry, chemical industry, diesel engines and similiar high reliability aggressive environments
Has good ozone resistance which makes it compaitible with high temperature, high pressure compressed air systems
Low temperature compounds are available down to -54 ºC / -65 ºF
Suitable with:
H2S (upto 10%), mineral oils and greases, LPG, fuel oils, water and steam resistance up to 149 ºC, dilute acids, glycol-based hydraulic fluids, vegetable oils, ozone, ageing, weathering
HYTREL® - THERMOPLASTIC POLYESTER ELASTOMER ( TCP - ET )
Trade names:
DuPont™ - Hytrel®, SKF Group - Fluorotrel®
Temp. Range:
-54 ºC to +149 ºC
-65 ºF to +300 ºF
Description:
Hytrel (TPC-ET) is a thermoplastic elastomer material which has excellent strength and toughness properties. TPC-ET can be made as a very flexible or relatively hard material depending on the grade. TPC-ET is similiar to urethane.
Demonstrates high resilience and flexiblity which permits easier installation than PTFE materials
Suitable with:
Mineral oils and greases, hydrocarbon fuels, water-based hydraulic fluids HFA and HFB, environmentally acceptable hydraulic fluids, glycol, dilute acids and bases
Perfluoroelastomers are a development of fluoroelastomers where the polymer chain is fully fluorinated so no hydrogen is present. Due to the raw materials for the production of these compounds being very expensive the materials remain as high cost specialist compounds.
FFKM's have the broadest chemcial resistance of any elastomeric material and very high temperature capability
FFKM's combine the sealing integrity of elastomers with chemical resistance approaching that of PTFE
FFKM's can suffer considerable loss of mechanical properties at high temperatures such as compression set
FFKM's are the most expensive elastomers
Kalrez 4079 - A low compression set 75 durometer compound with excellent chemical resistance, good mechanical properties and outstanding hot air aging properties
Kalrez Spectrum 6380 - An 80 durometer compound specifically developed for chemical processes involving hot, aggressive amines; in addition it has excellent overall chemical resistance
Kalrez Spectrum 7090 - A 90 durometer compound that is specifically targeted for use in applications requiring high hardness/higher modulus properties. This compound has excellent mechanical properties including compression set resistance and explosive decompression resistance
Compounds available to+325°C/+617°F
Suitable with:
Most Media
Not suitable with:
Liquid sodium and potassium, fluorinated solvents and refrigerants, some chlorine compounds, steam over 150 ºC depending on grade
-40 ºC to +120 ºC (Low Temp. - LTN available to -54 ºC)
-40 ºF to +248 ºF (Low Temp. - LTN available to -65 ºF)
Description:
The acrylonitrile content of nitrile sealing compounds varies between 18% and 50%. The higher the acrylonitrile content, the better the resistance to oils & fuels. At the same time, elasticity and compression set properties are adversely affected. So a compromise is often made and a medium acrylonitrile content selected.
Presently the most widely used elastomer in the seal industry
Provides an exceptional balance of good mechanical properties, wear properties and reasonable resilience
Nylon was the first synthetic material to be developed (1938).
Nylon, from Dupont, is a tough and abrasion resistant material which makes it useful for wear resistance in dry applications
Polyamide may be reinforced by fillers such as glass to provide higher strengh or could be filled with MoS2 to provide improved lubrication
A major limitation of polyamide is its high water absorption which leads to swelling of the material
Major applications are wear rings, bushings and anti-extrusion rings
Suitable with:
Air, mineral oils and greases
Not suitable with:
Water or high relative humidity, solvents, acids
POLYAMIDE-IMIDE ( PAI )
Trade names:
Solvay - Torlon®
Temp. Range:
-200 ºC to 260 ºC
-328 ºF to 500 ºF
Description:
Polyamide-imide materials provide the overall highest performance capability of any melt processable thermoplastic.
Torlon® offers good resistance to elevated temperatures as well as broad chemical resistance
Capable of performing under severe stress conditions at continuous temperatures up to 260°C
Has a low coefficient of thermal expansion and high creep resistance which contributes to dimensional stability
Machined Torlon parts provide greater compressive strength and higher impact resistance than most other engineering plastics
Suitable with:
Hydrocarbon oils, fuels and solvents including aromatics, some acids including sulphuric, chlorinated organics, some alcohols, ethylene glycol
Not suitable with:
Hot water or humid conditions, methanol, caustic fluids
POLYBENZIMIDAZOLE ( PBI )
Trade names:
Quadrant - Celazole® PBI
Temp. Range:
Up to 343 ºC
Up to 650 ºF
Description:
Celazole® (PBI) is the highest performance engineering thermoplastic available today.
It offers the highest heat resistance and mechanical property retention over 204 ºC (400 ºF) of any unfilled plastic
It offers the highest heat deflection temperature 427 ºC (800 ºF), with a continous service capability of 399 ºC (750 ºF) in inert environments, or 343 ºC (650 ºF) in air with short term exposure potential to 538 ºC (1000 ºF)
It has the lowest coefficient of thermal expansion and highest compressive strength of all unfilled plastics
Good in environments where better wear resistance and load carrying capabilities are required
Acts as an excellent thermal insulator
Suitable with:
Not suitable with:
POLYETHERETHERKETONE ( PEEK )
Trade names:
Victrex® - Victrex® PEEK™, Quadrant - Ketron®
Temp. Range:
-70 ºC to +260 ºC
-94 ºF to +500 ºF
Description:
PEEK compounds have a temperature range similiar to that of PTFE but they have a much higher strength and also retain their mechanical properties to high temperatures. PEEK has good hydrolysis resistance and its chemical resistance is close to that of PTFE.
PEEK is extensively used as a backup ring material for high pressure, high temperature applications dues to its hardness
A wide variety of grades are available including glass-filled PEEK
Suitable with:
Most Media
Not suitable with:
Some acids including hydrochloric, nitric and sulphuric, some phenols and sulphur compounds
POLYETHYLENE ( UHMW-PE )
Trade names:
Quadrant - Tivar®
Temp. Range:
-250 ºC to + 80 ºC
-418 ºF to +176 ºF
Description:
Ultra high molecular weight polyethylene has extreme wear resistance and has been found to give superior performance to PTFE in water applications. It has also been found to give good service in cryogenic seals.
Commonly used as wear rings, valve seats and in high speed sealing applications
Good impact resistance
Excellent abrasion resistance
A low coefficient of friction
A non-sticking and self-lubricating material with excellent mechanical properties
Suitable with:
Water, aqueous solutions, aromatic hydrocarbons
Not suitable with:
Strong acids and alkalis, esters, chlorine, chlorinated hydrocarbons, refrigerants, amines
POLYETHYLENE ( Low Density - LDPE )
Trade names:
Temp. Range:
-70 ºC to 80 ºC
-94 ºF to +176 ºF
Description:
Created through the high pressure polymerization of thylene, its low density is due to the presence of a small amount of branching in the molecular chain. This creates a virtually unbreakable product with extreme flexibility. Low density polyethelene varies in colour from translucent to opaque, and is suited for a wide range of molded applications.
The material of choice for laboratory dispensers and wash bottles due to its excellent flexibility and non breakable properties
Used extensively in film applications for packaging as bags, bottles, lids and caps
Also used as an extrusion coating, sheathing for cables and in extrusion and injection molding
Suitable with:
Acids, Alcohols, Bases, and Esters, Aldehydes, Ketones, and Vegetable oils
Not suitable with:
Aliphatic and Aromatic Hydrocarbons, Mineral Oils, Oxidizing Agents, Halogenated Hydrocarbons.
PPS is a high temperature, high strength plastic with good chemical resistance. Although temperature and fluid resistance is not as comprehensive as PTFE it has higher strength and is a useful economic alternative.
It is used for backup rings and also as a V-ring material in oilfield applications
Used as a high temperature structural plastic for automotive components
Some 50 % of production is for automotive components including brake, coolant and fuel systems and in the power train and transmission
Used for components such as plastic pistons, valve bodies and the housing of integral seals and gaskets
Fluid resistance can be limited by the filler so it is important to assess individual grades for actual compatibility
Suitable with:
Water, mineral and synthetic oils, automotive coolants and brake fluids, non-oxidizing aqueous acids, non-oxidizing organics, bases and salts, refrigerants at low temperature
Not suitable with:
Oxidizing chemicals, strong acids, chlorine, chlorinated solvents, refrigerants at elevated temperature
POLYURETHANE ( AU , EU )
Trade names:
SKF Group - Lubrithane®
Temp. Range:
-54 ºC to +105 ºC
-65 ºF to + 221 ºF
Description:
Polyurethane is a thermoplastic elastomer and its tensile strength and wear resistance is typically 2-3 times higher than comparable elastomers such as nitirle. Polyurethane materials also have good resilience.
Polyurethane will maintain effective dynamic sealing at high pressures for extended periods
Widely used for both hydaulic and pneumatic reciprocating seals
The potential for plastic flow at high temperatures means polyurethane is not suitable for use as a typical rotary seal as the high underlip temperature will cause plastic flow
As polyurethane is a thermoplastic material it will only have elastomeric properties within a limited temperature range
At low temperatures it will have limited flexibility while at high temperatures it will be subject to plastic flow
Polyurethane suffers from hydrolysis in hot water and this can limit potential applications
There are two types of polyurethane, one based on polyester (AU) and the other on polyether (EU)
Polyester (AU) based materials provide the best oil and fuel resistance, wear and dynamic properties and have a longer shelf life (Approx 30 Yrs.)
Polyether (EU) based materials provide better hydrolysis resistance and are a little more flexible; they have a shorter shelf life (Approx. 7-10 Yrs.)
Polyester (AU) and Polyether (EU) urethanes are either used individually or in combination to optimize seal properties
The polyseal has a polyester (AU) base
Suitable with:
Most petroleum based fluids, water up to 65 ºC (149 ºF)
Dow Corning - Silastic®, GE Silicones - Silopren® and Silplus®, Wacker - Elastosil®
Temp. Range:
-65°C to +232°C
-85°F to +450°F
Description:
Silicone elastmers possess a wide temperature range. Their major problem is the relatively poor tensile strength and tear resistance which in turn makes them susceptible to wear and also more prone to damage on assembly.
Excellent resistance to oxidation and ozone degradation
Most commonly used in static applications
Popular for food and medical applications
Suitable with:
Mineral oils, vegetable oils, brake fluids, water, ozone, ageing, weather
Not suitable with:
Aromatic hydrocarbons and solvents, water and steam (>120ºC), acids, alkalis
TEFLON® - POLYTETRAFLUOROETHYLENE ( PTFE )
Trade names:
DuPont™ - Teflon®
Temp. Range:
-200°C to +250°C
-328°F to +482°F
Description:
PTFE and its derivatives [ETFE, FEP (Fluorinated Ethylene-Propylene), PFA (Perfluoroalkoxy)] are perhaps the most widely used plastics in sealing technology. In unfilled (virgin) form it is relatively soft and will conform to the surface texture to provide a low leakage seal.
PTFE has virtually universal chemical resistance
Very low coefficient of friction with excellent dry running properties
Low water absorption
Low dielectric constant and dissipation factor
It is found in both dynamic and static seals
Fillers can be incorporated to provide improved compression strength, heat, wear, creep and extrusion resistance
The different types of PTFE available are Virgin, Bronze, Glass, Moly-Glass and Carbon Graphite filled --these fillers are added to alter PTFE's sealing properties
NOTE: With filled PTFE the fluid resistance will be dictated by the filler material
Suitable with:
Most Media
Not suitable with:
Molten alkali metals, fluorine and other halogens, strong oxidizing agents